Journal
CHEMISTRY OF MATERIALS
Volume 14, Issue 2, Pages 773-776Publisher
AMER CHEMICAL SOC
DOI: 10.1021/cm010628o
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Binary mixtures of the aggregating helicene 1 with dodecane have, at dodecane concentrations >30 vol %, a nematic liquid crystalline phase and, at dodecane concentrations less than or similar to5 vol %, a hexagonal columnar liquid crystalline phase. The helical structure with donor and acceptor groups at opposite ends gives rise to a molecular dipole moment that is parallel to the helix axis and a positive dielectric anisotropy. Accordingly, the helix axes orient parallel to an applied electric field, providing the basis for electro-optic switching.
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