Journal
SOLID STATE SCIENCES
Volume 4, Issue 2, Pages 267-270Publisher
EDITIONS SCIENTIFIQUES MEDICALES ELSEVIER
DOI: 10.1016/S1293-2558(01)01225-0
Keywords
mixed-metal carboxylate; hybrid material; ferromagnetism
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MIL-45 or K[M-3(BTC)(3)].5H(2)O (M = Co, Fe) presents a hybrid 3D open structure based on undulating octahedral chains linked by two different trimesate anions. This compound exhibits ferromagnetic behaviour below 10 K for the pure Co phase and 20 K for the mixed-metal (Co, Fe) phase. (C) 2002 Editions scientifiques et medicales Elsevier SAS. All rights reserved.
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