4.3 Article

Tertiary amine-accelerated allylgallation of terminal alkynes

Journal

CHEMISTRY LETTERS
Volume -, Issue 2, Pages 172-173

Publisher

CHEMICAL SOC JAPAN
DOI: 10.1246/cl.2002.172

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Allylic gallium sesquibromides prepared by reduction of allylic bromides with gallium metal in the presence of a catalytic amount of indium, add to terminal alkynes with the aid of a tertiary amine to give 1,4-dienes.

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