Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 67, Issue 3, Pages 656-662Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo0106086
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Intermolecular coupling reactions of 1,3-dienes and aldehydes via transmetalation of nickelacycle intermediate with (BU2Al)-B-i-acac were investigated. In the reactions, a linear adduct or a branched adduct was produced, depending upon the nature of 1,3-dienes and aldehydes, via two nickelacycles that were relatively stable among the four possible nickelacycles because of the equilibrium with pi-allynickel forms.
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