Journal
AUSTRALIAN JOURNAL OF CHEMISTRY
Volume 66, Issue 4, Pages 443-451Publisher
CSIRO PUBLISHING
DOI: 10.1071/CH12464
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The syntheses of new silver complexes of five isomeric bis(pyridylmethyleneoxy)benzenes, differing in the position of substitution on the benzene and pyridine rings, and three isomeric 1,3,5-tris(pyridylmethyleneoxy)benzenes, differing in the position of substitution on the pyridine ring, are described. The structures of six of these complexes were characterised using X-ray crystallography, showing the formation of coordination polymers for 3-pyridyl- and 4-pyridyl-armed ligands and discrete complexes for 2-pyridyl-armed ligands. The precise nature of the structure was further determined by the relative orientation of the pyridine rings in each case.
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