4.4 Article

Olefin isomerization by a ruthenium carbenoid complex. Cleavage of allyl and homoallyl groups

Journal

TETRAHEDRON LETTERS
Volume 43, Issue 10, Pages 1839-1841

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4039(02)00141-7

Keywords

alkenes; isomerization; protecting groups

Ask authors/readers for more resources

Ruthenium-carbenoid catalysts such as Grubbs' complex I mediate efficiently the isomerization of beta,gamma-unsaturated ethers and amines to the corresponding vinyl ethers and enamines. This reaction can be useful in the deprotection of allyl and homoallyl ethers as well as amines. (C) 2002 Elsevier Science Ltd. All rights reserved.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.4
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

No Data Available
No Data Available