Journal
AUSTRALIAN JOURNAL OF CHEMISTRY
Volume 63, Issue 7, Pages 1013-1047Publisher
CSIRO PUBLISHING
DOI: 10.1071/CH10113
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Funding
- Deutsche Forschungsgemeinschaft
- Fonds der Chemischen Industrie
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Within the past four decades, matrix isolation spectroscopy has emerged as the method of choice for obtaining direct structural information on benzynes and related dehydroaromatics. In combination with quantum chemical computations, detailed insight into the structure and reactivity of di-, tri-, and tetradehydrobenzenes has been obtained. This Review focuses on rather recent developments in aryne chemistry with a special emphasis on the matrix isolation of tridehydrobenzenes and related systems.
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