Single-crystal to Single-crystal Transformations - Guest Removal and Substitution in a Robust Solvent-templated Metallocyclic Compound

The formation, structure, and single-crystal to single-crystal transformations of the dinuclear metallocycle [Ag2L2](PF6)(2)center dot 2CH(3)CN (L= 2,3,5,6-tetrafluoro-1,4-bis(2-methylimidazole-1-yl-methyl)benzene) are described. The acetonitrile guest molecules can be removed without loss of single crystallinity to afford a porous material. CO2 sorption isotherms were recorded at various temperatures and the structures and sorption behaviour of the crystals are compared with those of a previously reported analogous system. Upon exposure to acetone vapour, the desolvated crystals undergo a single-crystal to single-crystal transformation to form the acetone solvate.