Journal
AUSTRALIAN JOURNAL OF CHEMISTRY
Volume 63, Issue 5, Pages 845-848Publisher
CSIRO PUBLISHING
DOI: 10.1071/CH10014
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- Engineering and Physical Sciences Research Council [EP/D029538/1] Funding Source: researchfish
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A range of ionic liquids was prepared by mixing 1-alkyl-3-methylimidazolium chloride with gallium(III) chloride or indium(III) chloride in various ratios, producing both acidic and basic compositions. Their speciation was investigated using (71)Ga NMR or (115)In NMR spectroscopy, as well as extended X-ray absorption fine structure. Polynuclear Lewis acidic anions, [M(x)Cl(3x+1)](-), were found in chlorogallate(III) ionic liquids, but not in chloroindate(III) systems.
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