Journal
TETRAHEDRON
Volume 58, Issue 11, Pages 2239-2243Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4020(02)00097-2
Keywords
pyrogallo[4]arene; template reaction; ESI-MS; complexation; ion-selective membrane electrodes
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A template method for the synthesis of methoxypyrogallo[4]arene was presented. A complexation of MPA with strong electron acceptors was observed. The ESI-MS analysis showed strong complexing properties of MPA towards alkali metal cations. The ionophore properties of MPA were investigated. The quantum-mechanical calculations were performed for the resulting complexes. (C) 2002 Elsevier Science Ltd. All rights reserved.
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