Journal
TETRAHEDRON-ASYMMETRY
Volume 13, Issue 3, Pages 325-331Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0957-4166(02)00094-0
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A new MOP ligand 8 containing two it-octyl groups at the 6 and 6' positions of the (R)-2-(diphenylphosphino)-2'-aryl-1,1'-binaphthyl skeleton was prepared and used for the palladium-catalyzed asymmetric hydrosilylation of 1,3-dienes with trichlorosilane. The introduction of the n-octyl groups made the palladium-phosphine catalyst soluble in the reaction system, realizing high catalytic activity at a low reaction temperature. As a result, ligand 8 showed highest enantioselectivity for both cyclic and linear 1,3-dienes. (C) 2002 Elsevier Science Ltd. All rights reserved.
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