Journal
ORGANIC LETTERS
Volume 4, Issue 6, Pages 1031-1033Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol0256318
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[GRAPHICS] A newly developed strategy for eight-membered carbocycles via [3 + 4] annulation that involves the combination of beta-substituted acryloylsilanes and enolates of cycloheptenone is described. A unique feature of this annulative approach is its capacity to generate, in two steps, eight-membered ring systems containing useful functionalities for further synthetic elaboration from readily available three- and four-carbon components.
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