Journal
INORGANICA CHIMICA ACTA
Volume 331, Issue -, Pages 194-198Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/S0020-1693(01)00806-4
Keywords
chirality; copper complexes; Schiff base ligands; crystal structures
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Reaction of copper(II) acetate with the (S)-enantiomer of a tridentate binaphthyl Schiff base ligand. 2-(3,5-dichloro-2-hydroxybenzylideneamino)-2'-hydroxy-1,1'-binaphthyl (H2L), in methanol afforded mononuclear copper(II) complex [Cu-2(II)(HL)(2)] ((S,S)-1) in 52% isolated yield. The same reaction gave dinuclear copper(II) complex [Cu-2(II)(L)(2)] ((R,S)-2) in 73% isolated yield when racemic-H2L was used instead of (S)-H2L. Both complexes (S,S)-1 and (R,S)-2 were characterized by elemental analysis, mass spectrometry, and X-ray crystallography. The present work highlights the functioning of ligand chirality as a 'switch' for selective formation of mono- and dinuclear metal complexes. (C) 2002 Elsevier Science B.V. All rights reserved.
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