4.1 Article

Crystal structure and complexing properties of p-tert-butylcalix[6]-1,4-2,5-bis(crown-4)

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Publisher

SPRINGER
DOI: 10.1023/A:1016088905683

Keywords

cyclophanes; calixarenes; calixcrowns; ammonium complexation

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The X-ray structure of the already published p-tert-butylcalix[6]-1,4-2,5- bis(crown-4) 1 is reported. Extraction of solid ammonium picrate in chloroform-d indicates the cation to be located outside of the calixcrown and forming a 1:2 (metal-ligand) complex.

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