Journal
JOURNAL OF MATERIALS SCIENCE
Volume 37, Issue 7, Pages 1413-1420Publisher
KLUWER ACADEMIC PUBL
DOI: 10.1023/A:1014537000690
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Pr-ZrSiO4 yellow ceramic pigment is believed to be a solid solution of Pr4+ with the zircon lattice, but studies are poor and scarce. The aim of this paper is the synthesis of Pr-ZrSiO4 yellow pigment in the presence of NaF by several non-conventional methods and to investigate the nature of the pigment. Results indicate that the formation of Pr-ZrSiO4 yellow pigment must be explained by two simultaneous mechanisms: formation of a solid solution of Pr in a ZrSiO4 network and an occlusion mechanism. (C) 2002 Kluwer Academic Publishers.
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