4.5 Article

A substrate-unspecified glycosylation reaction promoted by copper(II) trifluoromethanesulfonate in benzotrifluoride

Journal

CARBOHYDRATE RESEARCH
Volume 337, Issue 7, Pages 581-585

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/S0008-6215(02)00029-0

Keywords

glycosylation; copper(II) trifluoromethanesulfonate

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A glycosylation reaction induced by copper(II) trifluoromethanesulfonate is described. Using benzotrifluoride as the reaction solvent. five kinds of glycosyl donors, a glucosyl chloride, a fluoride, a trichloroacetimidate, a 1-O-acetyl compound. and a lactol were activated to give the corresponding glucosides. (C) 2002 Elsevier Science Ltd. All rights reserved.

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