Journal
JOURNAL OF ORGANOMETALLIC CHEMISTRY
Volume 649, Issue 1-2, Pages 9-14Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/S0022-328X(01)01427-9
Keywords
boryl; boron; iron; manganese; hydrogen bond; substitution
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The synthesis and characterization of iron and manganese complexes containing the tetrachlorocatecholboryl (BO2C6Cl4) ligand are reported. Crystallographic study of the methylcyclopentadienyl derivative (eta(5)-C5H4Me)Fe(CO)(2)BO2C6Cl4 allows comparison of structure and bonding with related complexes of the type (eta(5)-C5R5)Fe(CO)(2)B(OR)(2) and reveals that the relative orientation of (eta(5)-C5H4Me)Fe(CO)(2) and BO2C6Cl4 moieties is influenced by intramolecular C-(HO)-O-... hydrogen bonding, Additionally, an alternative route to catecholboryl complexes from dilithiocatechol is reported. (C) 2002 Elsevier Science B.V. All rights reserved.
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