Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 67, Issue 8, Pages 2723-2726Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo0163851
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Caged analogues of biologically active compounds have received widespread attention as temporally and spatially controlled probes of cell-based processes. Recently, a coumarin-4-ylmethyl derivative has been used to cage carboxylates, sulfonates, carbamates, and phosphates. We describe herein a synthetic strategy that furnishes photosensitive caged diols and provides an entry into the protection/photodeprotection of functionality with modest leaving group abilities.
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