Journal
JOURNAL OF ORGANOMETALLIC CHEMISTRY
Volume 649, Issue 2, Pages 289-292Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/S0022-328X(01)01461-9
Keywords
iridium catalyst; pentamethylcyclopentadienyl complex; oxidation; hydrogen transfer
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The oxidation of primary and secondary alcohols is carried out in acetone under mild conditions using catalytic amounts of [Cp*IrCl2](2) and K2CO3. Primary alcohols are converted into the corresponding aldehydes with high selectivity in good yields. Secondary alcohols are readily oxidized to ketones with smaller amounts of the catalyst. (C) 2002 Elsevier Science B.V. All rights reserved.
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