Journal
TETRAHEDRON LETTERS
Volume 43, Issue 18, Pages 3381-3383Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4039(02)00472-0
Keywords
marine metabolites; antitumor compounds; macrolactonization; allylsilane addition; chiral acetal
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A stereocontrolled synthesis of the title compound is described. Key steps are an allylsilane addition to a chiral acetal as the major coupling step and a Yamaguchi macrolactonization for ring closure. (C) 2002 Elsevier Science Ltd. All rights reserved.
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