Journal
JOURNAL OF ORGANOMETALLIC CHEMISTRY
Volume 650, Issue 1-2, Pages 173-180Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/S0022-328X(02)01213-5
Keywords
hydrostannation; vinylstannanes; radical; palladium catalysis; stereoselectivity
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Hydrostannation of mono- and disubstituted alkynes with trineophyltin hydride (1) leads to vinylstannanes in good to excellent yields, the configuration of the products depending on the reaction conditions. Thus. whereas hydrostannation. under radical conditions leads stereoselectively to only one of the two possible products corresponding to an anti addition ill 60-99%. yield, the additions catalyzed by bis(triphenylphosphine)palladium dichloride gave mixtures of the syn adducts (60-79% yield). Full H-1-,C-13- and Sn-119-NMR as well as mass spectra data of the organotin adducts are given. (C) 2002 Elsevier Science B.V. All rights reserved.
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