Journal
RUSSIAN JOURNAL OF GENERAL CHEMISTRY
Volume 72, Issue 5, Pages 693-695Publisher
MAIK NAUKA/INTERPERIODICA
DOI: 10.1023/A:1019539730979
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The density of the water-N,N-dimethylformamide mixture throughout the entire range of compositions in the temperature range 278.15-323.15 K at atmospheric pressure (0.101 MPa) was measured. The coefficients of thermal dilatation alpha were calculated. The alpha value strongly depends on the composition of the mixture in the range 0 < X < 0.3 (X is the molar fraction of dimethylformamide), which is associated with breakdown of water structure. An equation relating the molar volume of the water-dimethylformamide mixture to the composition of the mixture and to the temperature was proposed.
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