Journal
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION A-A JOURNAL OF PHYSICAL SCIENCES
Volume 57, Issue 5, Pages 277-280Publisher
WALTER DE GRUYTER GMBH
DOI: 10.1515/zna-2002-0512
Keywords
XAFS; molten salt; zirconium tetrachloride; coordination
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The local structure of motlen ZrCl4 in LiCl-KCl eutectic was investigated by using an X-ray absorption fine structure (XAFS) of the Zr K-absorption edge. The nearest Zr4+-Cl- distance and coordination number from the curve fitting analysis were (2.51 +/- 0.02) Angstrom and 5.9 +/- 0.6, respectively. These suggest that a 6-fold coordination (ZrCl6)(2-) is predominant in the molten mixture.
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