Journal
JOURNAL OF THE CERAMIC SOCIETY OF JAPAN
Volume 110, Issue 5, Pages 501-505Publisher
CERAMIC SOC JAPAN-NIPPON SERAMIKKUSU KYOKAI
DOI: 10.2109/jcersj.110.501
Keywords
nickel manganese double hydroxide; lithium insertion malerial; spinel; lithium-ion cell
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A five-volt lithium insertion material of Li[Ni1/2Mn3/2]O-4, having a spinel-framework structure, was prepared from nickel manganese double hydroxide with LiOH and characterized by XRD, FT-IR, TG, SEM and electrochemical methods. Heating a reaction mixture below 600degreesC did not give good results in terms of polarization and cycleability during charge and discharge in lithium nonaqueous cells. Higher heating temperatures gave lower polarization and better cycleability, while rechargeable capacity at 4.75 V vs. Li reduces as heating temperature rises. After several trials, an optimum condition to prepare a five-volt lithium insertion material of Li[Ni1/2Mn3/2]O-4 is found to be a two-step solid state reaction, i.e., crystallization at 1000degreesC followed by oxidation at 700degreesC. By this process Li[Ni1/2Mn3/2]O-4 showed an excellent performance in a five-volt nonaqueous lithium cell and also in a three-volt lithium-ion cell with a Li[Li1/3Ti5/3]O-4-negative electrode.
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