Journal
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY
Volume 58, Issue -, Pages M273-m274Publisher
INT UNION CRYSTALLOGRAPHY
DOI: 10.1107/S0108270102003797
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In the title complex, [RuCl2(C7H7NO)(C2H6OS)(2)], the metal ion is at the centre of a distorted octahedral NOCl2S2 coordination sphere. The neutral 2-acetylpyridine ligand binds to the metal ion through the pyridine N and carbonyl O atoms, forming a five-membered chelate ring. The monodentate S-coordinating dimethyl sulfoxide molecules are mutually cis, and the two remaining positions in the coordination sphere are occupied by two mutually trans Cl- ions.
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