Journal
INTERMETALLICS
Volume 10, Issue 5, Pages 519-521Publisher
ELSEVIER SCI LTD
DOI: 10.1016/S0966-9795(02)00015-8
Keywords
intermetallics; miscellaneous; crystallography; magnetic properties
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The crystal structure of binary UNi4 was studied from single crystal X-ray diffraction data. This compound crystallises with CaCu5 structure type (space group P6/mmm), with the unit-cell dimension: a = 4.8457(2) (A) over circle, c = 4.0451(2) (A) over circle. This phase belongs to the limited solid solution U1+x Ni5-x with 0.20 < x < 0.33, where U atoms substitute partially Ni on its two crystallographic sites. UNi4 is paramagnetic down to 4.2 K. (C) 2002 Elsevier Science Ltd. All rights reserved.
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