Journal
ORGANIC LETTERS
Volume 4, Issue 9, Pages 1583-1585Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol0258076
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- NCI NIH HHS [CA67775, CA44848] Funding Source: Medline
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A new sesterterpene epoxide-diol, aspergilloxide (1), was isolated from the extract of a cultured marine-derived fungus (strain CNM-713) identified as an undescribed member of the genus Aspergillus. The structure of 1 was determined by interpretation of NMR data and by chemical methods. The absolute stereochemistry of aspergilloxide was assigned by application of the modified Mosher method. The carbon skeleton of 1 represents a new addition to the architectural diversity of the sesterterpenoid (C-25) class of secondary metabolites.
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