Journal
ORGANIC LETTERS
Volume 4, Issue 9, Pages 1411-1414Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol017245g
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[GRAPHIC] The first examples of N-carbamoyl-substituted heterocyclic carbene Pd(II) complexes are described, These thermal and hydrolytically stable complexes are readily prepared from carbamoyl imidazolium salts and efficiently promote Sonogashira cross-coupling reactions under mild conditions. Cesium carbonate is also shown to be an effective base for the coupling of aryl bromides.
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