Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 67, Issue 9, Pages 2751-2754Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jo016025d
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- NCI NIH HHS [R01 CA90383] Funding Source: Medline
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A total synthesis of the cytotoxic polyketide marine natural product callystatin A is described. The route features chiral allenylmetal additions to construct the polypropionate C15-22 segment and an sp(2)-sp(3) Suzuki coupling to join the C1-C11 and C12-C22 subunits.
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