4.4 Article

Novel reaction patterns of carbon disulfide with organolithium compounds via cleavage of C=S bonds or via cycloaddition reactions

Journal

TETRAHEDRON LETTERS
Volume 43, Issue 19, Pages 3533-3535

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4039(02)00581-6

Keywords

carbon disulfide; lithium compounds; C=S cleavage; cycloaddition; sulfur heterocycles

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Carbon disulfide reacted at room temperature with 1,4-dilithio-1,3-diene species via cleavage of the C-S double bonds affording multiply substituted thiophenes or via cycloaddition reactions affording thiopyran-2-thiones. (C) 2002 Elsevier Science Ltd. All rights reserved.

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