4.4 Article

New approaches to fluorinated ligands and their application in catalysis

Journal

TETRAHEDRON
Volume 58, Issue 20, Pages 3889-3899

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4020(02)00213-2

Keywords

fluorinated ligands; fluorinated phosphines; fluorinated polymers; C-C coupling; fluorous catalysis; supercritical CO2

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Simple and generic approaches to fluorous soluble ligands have been developed and applied to the synthesis of various fluorinated arylphosphines including polymeric ones. The utility of some of these ligands has been demonstrated in catalysis in supercritical CO2 (scCO(2)) and fluorous solvents. (C) 2002 Elsevier Science Ltd. All rights reserved.

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