4.6 Article

Nucleation at liquid | liquid interfaces:: galvanostatic study

Journal

JOURNAL OF ELECTROANALYTICAL CHEMISTRY
Volume 526, Issue 1-2, Pages 29-35

Publisher

ELSEVIER SCIENCE SA
DOI: 10.1016/S0022-0728(02)00763-5

Keywords

nucleation; electrodeposition; nanoparticles; palladium; ITIES; liquid vertical bar liquid

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Electrochemical nucleation at a liquid I liquid interface has been studied by cyclic voltammetry and galvanostatic measurements. A model of general applicability to any current/potential transient was developed for three-dimensional nucleation and growth, yielding information on particle number density. The experimental data was analyzed with this model. (C) 2002 Elsevier Science B.V. All rights reserved.

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