Journal
CHEMICAL PHYSICS LETTERS
Volume 358, Issue 1-2, Pages 87-95Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/S0009-2614(02)00590-0
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The magnetic properties of a series of hydrated and dehydrated spin crossover compounds derived from the 2,6-bis(pyrazol-3-yl)pyridine (bpp) ligand have been reinvestigated and the light-induced crossover studied at 10 K. The capacity of a compound to retain the light-induced HS information has been estimated through the determination of the T(LIESST). The position of each compound in the T(LIESST)-T(1/2) diagram has been analyzed and the effect of the nature of the salt, hydration degree and cooperativity have been discussed. (C) 2002 Published by Elsevier Science B.V.
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