Journal
ORGANIC LETTERS
Volume 4, Issue 11, Pages 1951-1953Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol025971t
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[GRAPHICS] Catalytic enantioselective allylation with a chiral bisphosphoramide was applied to the synthesis of LY426965, a serotonin antagonist. The key step, addition of a 3,3-disubstituted allyltrichlorosilane to benzaldehyde, provided the adduct containing a stereogenic quaternary center with excellent diastereoselectivity and enantioselectivity.
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