Contributions of low molecular weight carboxylic acids to aerosols and wet deposition in a natural subtropical broad-leaved forest environment

The carboxylic acid component of autumn aerosol and wet deposition (fog water and rainwater) in a broad-leaved forest in central Taiwan was investigated. High levels of low molecular weight carboxylic acids (LMWCAs) were noted in all deposition types. Acetic acid, oxalic acid and formic acid were the most prevalent carboxylic acids, together accounting for 72.2% (fog water), 86.7% (rainwater), 77.2% (PM2.5) and 88.3% (PM2.5-10) of total carboxylic acid. The forest fog water contained 2453.9 +/- 1030.5 ng mL(-1) of carboxylic acid, 2.71 times more than was contained in forest rainwater. In PM, most carboxylic acid existed in the fine PM2.5 aerosol (576.6 +/- 254.1 ng m(-3) or 6.28 times more than was contained in PM2.5-10. Most carboxylic acids in PM had higher concentrations during the day. Pyruvic acid concentration was higher during the night (2.97 times), however, owing to its rapid photodegradation during the day. Citric acid accounted for 9.1% of the total carboxylic acid in fog water compared with just 1.8% in rainwater, confirming its origin from emissions from leaves. Raman spectroscopy was used to observe the photochemical conversion of citric acid into intermediate products and this observation confirmed that the carboxylic acids identified in the forest dry and wet depositions originated directly from biological emissions in the forest environment. (C) 2013 Elsevier Ltd. All rights reserved.