Fog chemistry in the Texas-Louisiana Gulf Coast corridor

Fog samples were collected in two population centers of the US Gulf Coast (Houston, Texas and Baton Rouge, Louisiana) using Caltech active strand cloud collectors. A total of 32 fogwater samples were collected in Baton Rouge (November 2004-February 2005) and Houston (February 2006). These samples were analyzed for pH, total and dissolved organic carbon, major inorganic ions, and a variety of organic compounds including organic acids, aromatics, carbonyls, and linear alkanes. Fogs in both environments were of moderate density, with typical fog liquid water contents < 100mgm(-3). Fog samples collected in Houston reflect a clear influence of marine and anthropogenic inputs, while Baton Rouge samples also reflect agricultural inputs. The volume-weighted mean fog pH was somewhat more acidic (similar to 4.3) in Houston than in Baton Rouge (similar to 5.0). A wide pH range was observed in fog at both locations. Houston fog had higher concentrations of Cl(-), NO(3)(-), Na(+), Mg(2+), and Ca(2+). Sulfate to nitrate ratios were high in fogs at both locations, typical of many clouds in the eastern US. Total organic carbon concentrations were much higher in Houston fogs than in Baton Rouge fogs. Efforts to speciate dissolved organic carbon (DOC) reveal large contributions from organic acids and carbonyls, with smaller contributions from other organic compound families including aromatics, alkanes, amides, and alcohols. Approximately 40% of the fog DOC was unspeciated in samples from both study locations. (c) 2007 Elsevier Ltd. All rights reserved.