4.4 Article

Stereoselective synthesis of (6R)- and (6S)-diosphenol and Ψ-diosphenol

Journal

TETRAHEDRON
Volume 58, Issue 26, Pages 5307-5315

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4020(02)00492-1

Keywords

terpenoids; stereoselection; reduction; regioselection

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Methods are discussed for the stereoselective synthesis of the (R)-and (S)-enantiomers of the diosphenols (5)-(8) by utilizing the commercially available stereoisomers (9), (12), (23) and (25) of carvone and limonene, respectively, as chiral starting materials. (C) 2002 Elsevier Science Ltd. All rights reserved.

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