Journal
ORGANIC LETTERS
Volume 4, Issue 13, Pages 2209-2211Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol026050l
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In the presence of GaCl3, silyl enol ethers are ethynylated at the alpha-carbon atom with chlorotrimethylsilylethyne. This reaction can provide alpha-ethynylated aryl ketones possessing acidic alpha-protons without isomerization to conjugated allenyl ketones.
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