4.4 Article

A study of electrochemical kinetics of lithium ion in organic electrolytes

Journal

KOREAN JOURNAL OF CHEMICAL ENGINEERING
Volume 19, Issue 4, Pages 638-644

Publisher

KOREAN INST CHEM ENGINEERS
DOI: 10.1007/BF02699310

Keywords

lithium ion batteries; RDE; electrolyte; limiting current density; diffusion coefficient

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Limiting current densities equivalent to the transport-controlling step of lithium ions in organic electrolytes were measured by using a rotating disk electrode (RDE). The diffusion coefficients of lithium ion in the electrolyte of PC/LiClO4, EC : DEC/LiPF6 and EC : DMC/LiPF6 were determined by the limiting current density data according to the Levich equation. The diffusion coefficients increased in the order of PC/LiClO4

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