Journal
JOURNAL OF ORGANOMETALLIC CHEMISTRY
Volume 653, Issue 1-2, Pages 54-57Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/S0022-328X(02)01264-0
Keywords
cross-coupling; organoboron compounds; palladium(II) complexes
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Until recently, organoboronic acids have been of limited use in organic synthesis due to their low reactivity for ionic reactions. During the past two decades; however, it has become increasingly clear that they are valuable reagents capable of undergoing many carbon-carbon bond formations in organic syntheses. In 1979, catalytic carbon-carbon bond formation, via transmetalation between organoboron compounds and palladium(II) halides, was found to proceed in the presence of a base. (C) 2002 Elsevier Science B.V. All rights reserved.
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