Journal
TETRAHEDRON LETTERS
Volume 43, Issue 27, Pages 4809-4812Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/S0040-4039(02)00923-1
Keywords
macrocyclic ligand; Schiff-base; cobalt complex; X-ray crystallography; redox behavior
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New macrocyclic dinucleating ligands have been easily synthesized by Schiff-base condensation reaction with the appropriate aldehyde and amine using the boric ion template method. The ligands hake two N2O2 metal-binding sites which are doubly linked to each other with methylene spacers. The ligands chelate with Co2-, Cu2+ and Ni2+ to form dimetallic Compounds in high yields. (C) 2002 Elsevier Science Ltd. All rights reserved.
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