Journal
ELECTROCHEMISTRY COMMUNICATIONS
Volume 4, Issue 7, Pages 589-592Publisher
ELSEVIER SCIENCE INC
DOI: 10.1016/S1388-2481(02)00381-8
Keywords
anodic benzylic fluorination; oxidation potential; electron-donating group; electron-withdrawing group; stability of benzylic cation
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Anodic fluorination of toluene, ethylbenzene, and cumene derivatives was comparatively studied using Et4NF-4HF as a supporting electrolyte and a fluorine source. Anodic benzylic fluorination occurred except for some cumene derivatives and the yields of the fluorinated products greatly depended on the stability of benzylic cations. (C) 2002 Elsevier Science B.V. All rights reserved.
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