Journal
ORGANIC LETTERS
Volume 4, Issue 14, Pages 2361-2363Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol026091h
Keywords
-
Categories
Ask authors/readers for more resources
[GRAPHICS] A novel amino alcohol-based Ir bifunctional complex acts as an efficient catalyst for oxidative lactonization of 1,4- or 1,5-diols with a substrate-to-catalyst molar ratio of 200-1000 in acetone or butanone. The reaction proceeds with broad functional group tolerance to give lactone in high yield at room temperature. The catalyst precursor Cp*IrCl[OCH2C(C6H5)(2)NH2] is isolated and characterized by a single-crystal X-ray analysis.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available