Journal
CRYSTENGCOMM
Volume 4, Issue -, Pages 426-431Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b202217f
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Interconversion of chain co-ordination polymers [Ag(4,4'-bipy)](X)}(infinity) (X = NO3- or BF4-) in aqueous media has been studied by JR and H-1 NMR spectroscopy, transmission electron (TEM) and atomic force (AFM) microscopies and by X-ray powder diffraction (PXRD). The exchange leads to the formation of a pure crystalline phase of a new co-ordination polymer, and detailed TEM and AFM studies indicate a solvent-mediated rather than a solid-state mechanism for the exchange process.
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