Journal
BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN
Volume 75, Issue 8, Pages 1807-1814Publisher
CHEMICAL SOC JAPAN
DOI: 10.1246/bcsj.75.1807
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The reactions of ketene silyl acetals and sityl enol ethers in a CCl4 solution containing no promoter under ambient temperature, reflux, or photo-irradiation conditions afforded products via the addition of a trichloromethyl group to those silyl substrates. Polyhalides other than CCl4 were subjected to photoreactions in a hexane solution, resulting in the formation of carbonyl derivatives based on the addition of polyhalogenated alkyl groups.
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