4.8 Article

A chaotic electroosmotic stirrer

Journal

ANALYTICAL CHEMISTRY
Volume 74, Issue 15, Pages 3616-3625

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ac025601i

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Two-dimensional, time-independent, and time-dependent electroosmotic flows driven by a uniform electric field in a conduit with nonuniform xi potential distributions along its walls are investigated theoretically. The time-independent flow fields are computed with the aid of Fourier series. The series' convergence is accelerated so that highly accurate solutions are obtained with just a few terms in the series. The analytic solution is used to compute flow patterns for various distributions of the xi potential along the conduit's boundaries. Subsequently, it is demonstrated that by time-wise periodic alternations of the xi potentials, one can induce chaotic advection. Ibis chaotic flow can be used to efficiently stir and mix fluids in microfluidic devices.

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