Journal
SYNLETT
Volume -, Issue 8, Pages 1335-1337Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/s-2002-32973
Keywords
natural products; chiral sulfoxides; total synthesis; copper-coupling; Pummerer reaction
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The total synthesis of virol C 1 was accomplished using a diastereoselective carbonyl reduction induced by a chiral sulfoxide, a Pummerer rearrangement to give the corresponding aldehyde fragment, and coupling reactions using Wittig and Cadiot-Chodkiewicz protocols.
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