Journal
ORGANIC LETTERS
Volume 4, Issue 16, Pages 2675-2678Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol0261635
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[GRAPHICS] The first enantioselective total synthesis of (-)-tejedine (1) is reported. Tejedine is a seco-bisbenzyltetrahydroisoquinoline isolated in 1998 as a minor component from Berberis vulgaris. The synthesis was achieved using a strategy employing four key steps, including a chiral auxiliary-assisted diastereoselective Bischler-Napleralski cyclization.
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