Journal
THERMOCHIMICA ACTA
Volume 391, Issue 1-2, Pages 159-168Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/S0040-6031(02)00173-9
Keywords
borazane; aminoborane; borazine; thermal decomposition; coupled TG/MS
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The thermal decomposition of borazane BH3NH3 in the temperature range up to 500 K has been studied by differential scanning calorimetry (DSC) and thermogravimetry (TG) combined with the FTIR spectroscopic and mass spectrometric analysis of the gas phase. Above 340 K borazane is decomposed in stages as the temperature is increased. The exothermic decomposition is accompanied by the release of approximately 2.2 mol H-2/mol BH3NH3. This corresponds to a remarkable hydrogen storage density of 14.3 mass% related to the mass of borazane. In the gas phase above the solid decomposition residue monomeric aminoborane (BH2NH2), borazine (BHNH)(3), which is the boron-nitrogen analog of benzene, and traces of diborane B2H6 were found beside hydrogen. The release of significant quantities of borazine was observed only at temperatures above 400 K. (C) 2002 Elsevier Science B.V. All rights reserved.
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