Journal
ORGANIC LETTERS
Volume 4, Issue 17, Pages 2825-2827Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol026089q
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[GRAPHIC] A ruthenium catalyst precursor bearing a bulky and electron-donating pentamethylcyclopentadienyl (Cp-*) ligand, typically (CpRuH3)-Ru-*(PPh3), mediates hydrosilylation of several 1-alkynes with novel regioselectivity to give preferentially 2-silyl-1-alkenes.
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